isomerism - перевод на арабский
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isomerism - перевод на арабский

TYPE OF STRUCTURAL ISOMERISM IN WHICH A POLYATOMIC LIGAND OR MOIETY CAN BE CONNECTED VIA DIFFERENT ATOMS
Linkage isomers; Linkage Isomerism; Linkage isomer; Ambidentate isomerism

isomerism         
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  • Molecular models of cyclohexane in boat and chair conformations.  The carbon atoms are colored amber or blue according to whether they lie above or below the mean plane of the ring. The C–C bonds on the ring are light green.
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  • O}}: '''I''' 1-propanol, '''II''' 2-propanol, '''III''' ethyl-methyl-ether.
MOLECULE WITH IDENTICAL ATOMIC COMPOSITION AS ANOTHER, BUT WITH DIFFERENT STRUCTURES OR ORIENTATIONS
Isomers; Isomeric; Isomerism; Molecular isomerism; Chemical isomer; Isomerizing; Isomerized
‎ تَصاوُغ‎
isomerism         
  • 150px
  • Molecular models of cyclohexane in boat and chair conformations.  The carbon atoms are colored amber or blue according to whether they lie above or below the mean plane of the ring. The C–C bonds on the ring are light green.
  • center
  • center
  • 120px
  • 120px
  • 150px
  • O}}: '''I''' 1-propanol, '''II''' 2-propanol, '''III''' ethyl-methyl-ether.
MOLECULE WITH IDENTICAL ATOMIC COMPOSITION AS ANOTHER, BUT WITH DIFFERENT STRUCTURES OR ORIENTATIONS
Isomers; Isomeric; Isomerism; Molecular isomerism; Chemical isomer; Isomerizing; Isomerized
تَصاوُغ
isomeric         
  • 150px
  • Molecular models of cyclohexane in boat and chair conformations.  The carbon atoms are colored amber or blue according to whether they lie above or below the mean plane of the ring. The C–C bonds on the ring are light green.
  • center
  • center
  • 120px
  • 120px
  • 150px
  • O}}: '''I''' 1-propanol, '''II''' 2-propanol, '''III''' ethyl-methyl-ether.
MOLECULE WITH IDENTICAL ATOMIC COMPOSITION AS ANOTHER, BUT WITH DIFFERENT STRUCTURES OR ORIENTATIONS
Isomers; Isomeric; Isomerism; Molecular isomerism; Chemical isomer; Isomerizing; Isomerized
‎ تَصاوُغِيّ‎

Определение

Isomerism
·noun The state, quality, or relation, of two or more isomeric substances.

Википедия

Linkage isomerism

In chemistry, linkage isomerism or ambidentate isomerism is a form of isomerism in which certain coordination compounds have the same composition but differ in their metal atom's connectivity to a ligand.

Typical ligands that give rise to linkage isomers are:

  • thiocyanate, SCN – isothiocyanate, NCS
  • selenocyanate, SeCN – isoselenocyanate, NCSe
  • nitrite, NO2
  • sulfite, SO2−3

Examples of linkage isomers are violet-colored [(NH3)5Co-SCN]2+ and orange-colored [(NH3)5Co-NCS]2+. The isomerization of the S-bonded isomer to the N-bonded isomer occurs intramolecularly.

The complex cis-dichlorotetrakis(dimethylsulfoxide)ruthenium(II) (RuCl2(dmso)4) exhibits linkage isomerism of dimethyl sulfoxide ligands due to S- vs. O-bonding. Trans-dichlorotetrakis(dimethylsulfoxide)ruthenium(II) does not exhibit linkage isomers.